|
| 1. PHYSICAL
DATA |
|
BOILING POINT for Liquid at 1
ATM.:27 degrees C (80.6 degrees F) GAS DENSITY: Approx. 6.17 Kg/m3 (0.385 lb. /
ft3) LIQUID
DENSITY: 1.48 Kg/l (92.3 lb. / ft3) at 77 degrees F (25 degrees
C) RELATIVE
DENSITY(AIR = 1): 5.14 MOLECULAR WEIGHT: Approx. 150.7 PHYSICAL STATE: Pressurized
Liquid APPEARANCE
AND ODOR: Colorless volatile liquid with slight ether-like
odor VAPOR
PRESSURE OF LIQUID ALONE: (68 degrees F, 20 degrees C): Approx. 11.2
psig (77 kPa) PRESSURE OF MIXTURE IN CONTAINER: 95 psig @ 70 degrees F (655
kPa @ 20 degrees C) OCTANOL/WATER PARTITION COEFFICIENT (Log Pow):
2.0-2.8 |
|
| 2. FIRE AND EXPLOSION HAZARD
DATA |
|
FLASH POINT:
None FLAMMABILITY
LIMITS (LEL, UEL): Not Applicable AUTOIGNITION TEMPERATURE: Not
Determined EXTINGUISHING MEDIA: Non-Flammable SPECIAL FIRE FIGHTING PROCEDURES: Ensure that
the area where the fire occurred is well ventilated before re-entering.
Wear protective clothing. Use water spray or fog to cool storage
containers to help prevent an uncontrolled pressure
release. UNUSUAL
FIRE AND EXPLOSION HAZARDS: The concentrated agent when applied to fire
can produce toxic by-products specifically hydrogen halides which can
cause damage. Avoid inhalation of these materials by evacuating and
ventilating the area. |
|
| 3. REACTIVITY
DATA |
|
STABILITY: Stable under
normal conditions. Decomposes under fire conditions.
INCOMPATIBILITY (MATERIALS TO AVOID):
Reactive with Alkali and alkaline earth metals and powdered metals such
as aluminum and zinc. Avoid contact with oxidizers.
HAZARDOUS POLYMERIZATION: ( ) will
occur (X) will not occur HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Thermal decomposition
may produce hydrogen fluoride, hydrogen chloride, and carbonyl
halide. |
MATERIAL SAFETY DATA
SHEET
PAGE: 2 OF 3 PRODUCT NAME: Halotron
I
DATE: 1-30-98
|
| 4. HEALTH HAZARD
DATA |
| GENERAL
INFORMATION: |
- When using the material for prolonged
periods in filling or servicing operations, PERFORM THESE ACTIVITIES IN
A WELL VENTILATED AREA.
- Fire Extinguishers filled with this
material should be used in enclosed areas with a net room volume of
at least 140 cubic feet per pound of Halotron I in the
extinguisher.
|
| SYMPTOMS OF
EXPOSURE: |
- By inhalation: Exposure may cause
central nervous system effects such as dizziness, drowsiness,
anesthesia, or unconsciousness. Anesthetic effects may occur at
concentrations of 5000 ppm (v/v) or above. At concentrations of 20,000
ppm or higher, HCFC-123 may cause increased sensitivity of the heart to
adrenaline which might cause irregular heart beats and possibly
ventricular fibrillation or death.
- To the Eyes: Irritation and tearing
may result from the cooling effect of HCFC-123 evaporation to dissolve
fats, contact should be avoided.
- To the Skin: Evaporative cooling can
result in chilling sensations or frost bite efects. Repeated exposure to
the skin can result in dermatitis. Due to the ability of GCFC-123 to
dissolve fats, contact should be avoided.
- By ingestion: Not likely to occur in
industrial use. Highly volatile liquid.
- LISTED AS A CARCINOGEN: ( ) YES
(X ) NO
|
| TIME WEIGHTED EXPOSURE LIMITS (For
persons regularly exposed to material) |
- Workplace environmental Exposure
Level, WEEL (AIHA) (8 hrs): 50 ppm (v/v), based recommended on the
primary component (HCFC-123).
|
| TOXIC PROPERTIES OF COMPONENTS: Acute
toxicity is low. |
- For
2,2-dichloro-1,1,1-trifluoroethane (CAS #306-83-2):
LC50 (4 hr.): 3.2% (32,000
ppm), (Inhalation) Oral Approximate Lethal Dose (ALD): 9g/kg
(body weight) Cardiotoxic LOAEL (Lowest Observed Adverse
Effect Level): 2% Cardiotoxic NOAEL (No Observed Adverse Effect
Level): 1% Toxicological testing was performed on HCFC-123 by the Program
for Alternative Flourocarbon Testing (PAFT). Data from acute toxicity
studies in this program demonstrated that HCFC-123 has very low toxicity
by skin application or inhalation.
- For the proprietary gas mixture in
the absence of extreme temperature are primarily its ability to function
as a simple asphyxiant (i.e. displace oxygen).
|
|
| OTHER TOXICITY
INFORMATION: |
Animal Studies: For
2,2-dichlor0-1,1,1-triflouromethane (CAS #306-83-2):
Long
-term exposure in a two year study (6 hours/day, 5 days/week) at
concentrations of 300, 1000 and 5000 ppm decreased body weight, serum
cholesterol, triglycerides and glucose, and increased urinary flouride
concentrations in rats. However, survival was significantly improved in
all exposed groups compared to control animals. Inhalation of 300, 1000
and 5000 ppm caused an increase in benign tumors of the liver, pancreas,
and testis. Tumors occurred late in life and none were assessed to
be life threatening. Tumor formation is thought to occur through
non-genotoxic mechanisms associated with a peroxisome proliferating
potential or with hormonal disturbances in older rats. |
MATERIAL SAFETY DATA
SHEET
PAGE: 3 OF 3 PRODUCT NAME: Halotron
I
DATE: 1-30-98 ________________________________________________________________________________________________ |
|
| Exposure to
dogs, guinea pigs or monkeys at 1000 ppm or greater for 6 hrs./day, 7 days
per week, for a total of 3 weeks induced slight or mild liver damage with
altered anzyme levels.
Rodent studies
indicate HCFC-123 is easily absorbed via inhalation. It distributes
in all organs, more so in the liver. About 90% of inhaled
HCFC-123 is eliminated via the luyngs unchanged. The remaining
amount in metabolized to trifluoroacetic acid and excreted in the
urine. Small amounts of trifluoroacetylated proteins were detected
in rats.
HCFC-123 did
not affect reproductive performance in rats or harm the unborn animals in
rats or rabbits at 5000 and 10,000 ppm.
HCFC-123 was
inactive in several test-tube gnetic damage studies except the human
lymphocyte chromosome aberration assay. HCFC-123 is also inactive in
live animal genetic damage studies. Therefore, it is not
considered genotoxic.
RECOMMENDED FIRST AID FOR OVEREXPOSURE: (Use breathing apparatus if rescuing in an area
with high concentration)
Inhalation:
Remove person to area with fresh air. Apply artificial respiration if
necessary.
Contact a physician. Skin
Contact:
Apply large amounts of water, contact a physician.
Eye
Contact:
Apply large amounts of water, contact a physician.
Ingestion:
Induction of vomiting may pose a hazard. Contact a
physician.
Note to
Physician: Do not administer adrenaline or similar
drugs. |
|
| 5. PROTECTION
INFORMATION |
|
- Wear protective clothing when
handling a leak.
- Neoprene, PVC or PVA gloves should be
worn when handling.
- Protective eyeglasses and protective
shoes should be worn when handling.
- Respiratory protection is not
normally needed, however, if handling in enclosed spaces where
applicable exposure limits will be exceeded, a Self Contained Breathing
Apparatus (SCBA) should be used.
- When using the material for prolonged
periods in filling or servicing operations, PERFORM THESE ACTIVITIES IN
A WELL VENTILATED AREA.
|
|
| 6. SPILL, LEAKAGE, DISPOSAL AND
SPECIAL PRECAUTIONS |
|
- In the event of a spill, allow for
adequate ventillation, and do not re-enter an area without an SCBA until
adequate ventilation is accomplished.
- For spills that might result in
overexposure, evacuate the area and use protective gear and
SCBA's.
- Avoid leakage into water ways because
HCFC-1233 is damagingv to vegetation.
- Do not expose storage containers to
fire, as uncontrolled pressure releases may result.
- The HCFC-123 vapors are heavier than
air, therefore use caution when releases occur in low lying areas where
concentrated vapors may accumulate.
- Recommended 1 Hr. Emergency Exposure
Limit: 1000 ppm (v/v) on the same basis as above.
- Recommended 1 Min. Emergency Exposure
Limit: 2500 ppm (v/v) on the same basis as above.
WASTE DISPOSAL: Observe all
federal, state, and local regulations for products of this type when
accomplishing disposal. |
MATERIAL SAFETY DATA
SHEET
PAGE: 4 OF 3 PRODUCT NAME: Halotron
I
DATE: 1-30-98 ________________________________________________________________________________________________ |
|
|
|
 |
| 6. SPILL, LEAKAGE, DISPOSAL
AND SPECIAL PRECAUTIONS (cont.) |
|
| SECTION 313
SUPPLIER NOTIFICATION: This product contains more than 93% by weight
2,2-dichloro-1,1,1-trifluoroethane (CAS #306-83-2) which is subject to the
reporting requirements of section 313 of the Emergency Planning and
Community Right-To-Know Act of 1986 (40CFR372). |
|
|
|
| HAZARDOUS MATERIAL
IDENTIFICATION SYSTEM (HMIS): |
|
|
|
|
|
| Ratings: |
|
HMIS
Hazard Index: |
|
|
|
|
|
|
| HEALTH: |
1 |
MINIMAL: |
0 |
SEVERE:
4 |
| FLAMMABILITY: |
0 |
SLIGHT: |
1 |
|
| REACTIVITY: |
1 |
MODERATE: |
2 |
|
| PERSONNEL
PROTECTION: |
B |
SERIOUS: |
3 |
| PERSONAL PROTECTIVE
EQUIPMENT DESIGNATIONS:
A: Safety glasses B:
Safety glasses, gloves C: Safety glasses,
gloves, synthetic apron D: Face shield, gloves,
synthetic apron E: Safety glasses,
gloves, dust respirator F: Safety glasses,
gloves, synthetic apron, dust respirator G:
Safety glasses, gloves, vapor respirator H:
Splash goggles, gloves, synthetic apron, vapor
respirator I: Safety
glasses, gloves, combination dust and vapor respirator
J: Splash goggles, gloves, synthetic apron
combination, dust and vapor respirator K:
Airline hood or mask, gloves, full protective suit,
boots X: Situations
requiring specialized handling |
|
| 7.
TRANSPORTATION |
|
DOT SHIPPING
NAME: Compressed Gases, N.O.S, (contains Tetrafluoromethane,
argon), 2.2, UN1956 DOT SHIPPING LABEL: Nonflammable Gas
IMCO
CLASS:
2.2 |
|
| WARNING: Contains
HCFC-123, a substance which harms the public health and environment by
destroying ozone in the upper atmosphere. |
|
|
| The
information and recommendations in this publication represent our current
data and best opinion as to the proper use and handling of this material
under normal conditions. Any use of the described material which is not in
conformance with this publication or which involves using the described
material in combination with any other material or any other process is
the responsibility of the user. |
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